Method of and means for controlling the humidity within containers



.Fam 20 E924,

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J. WHITING METHOD OF AND MEANS FOR CONTROLLING THE HUMIDIWY` WITHIN CONTAINERS Filed May 17. 1921 Patented Jan. 29, 1924.

unirse STATES PATENT ori-uen.

JASPER WHITING, 0F BOSTON, MASSACHUSETTS.

METHOD 0F AND MEANS FOR; CONTROLLING THE HUMIDITY WITHIN CONTAINERS.

Application filed May 17, 1921. Serial No. 470,305.

yTo all whom it may concer/11,:

Be it known that I, JASPER WRITING, a citizen of the United States, residing at Boston, in the county of Suffolk and State of- Massachusetts, have invented certain new and useful Improvements in Methods ofand Means for Controlling the Humidity Within Containers, of which the following is a specification.

This invention relates to the control` of the humidity wit-hin containers.

The quality of various materials, such as cigars, tobacco, foodstuii's and various'other absorbent materials depends kto a considerable extent upon thedegree of humidity of the atmosphere surrounding the material.

A cigar which is too dry burns too rapidly and does not develop. that -peculiar aroma which is desired by fastidious smokers. 0n the other hand, if kept too moist it tends to develop mold.v Likewise bread, cake and -various other food products if too dry or too moist are not considered as palatable as the same products with a definite moisture content between the extremes.

During the course of their manufacture, certain materials such as tea and tobacco, require to maintained at a definite moisture content if'satisfactory results are to be obtained, as is well known. Brieiy the physical condition of -many absorbent substances is dependent upon their moisture content, which in turn depends mainly on the humidity of the air which surrounds them.

I am aware that various devices have been used for maintaining substantially dry air in closed containers, or for maintaining the air within a container at substantially 100% relative humidity.

Many materials, however, function best at some definite degree of humidity intermediate between complete saturation and complete dryness; and by my invention I aim to maintain the material at such a (definite degree of humidity.

It is the object of my invention to main tain within a closed container a fairly constant relative humidity or, moisture content, even though articles which are much wetter or, dryer than corresponds to the desired moisture content are placed from time to time Within the box.

This may be accomplished in an imperfeet manner by placing within the container a solution of some soluble material. If the concentration of the solution is properly adjusted, it will take up water from articles which are too wet or .give it ofi' to articles which are too dry.v The dif ficulty is, however, that the vapor pressure o f such solution changes, as it takes up or glves vofi' water, and so the vapor pressure which is maintained within the'container will not be constant, and the solution will have to be changed quite frequently, if even approximate constancy is to be maintained. l These difiiculties and inconveniences may be largely overcome by placing in the container a saturated solution of a salt in contact with a quantity of the salt in solid form. men thisV system takes up water the amount of the solution creased and the amount of the solid phase v correspondingly decreased, but the concentration of the solution, and consequently the vapor pressure, remains unchanged until one or the other of the two phases disappears. The use of such a s stem. permits the use of a relatively email of solution and the maintenance of a Substantially constant vapor tension with less frequent readjustment of the system.

The use of solutions or finely divided solids is, moreover, open to certain mechanical and practical diiculties and disadvantages which render them unsuitable to commercial use. Thus solutions within containers are likely to contaminate the articles contained by being overturned, by accident or otherwise. Besides, the use of a solution .in such container is a slow lmethod of accomplishing the purpose since the amount of surface exposed to the air is relatively small and therefore, the rate of absorption or evaporation 'of moisture is correspondingly low.

It is a more particular object of the in vention to provide a method of and means for maintaimng a relatively high humidity phase is merely in-v quantity in a container without the disadvantages above pointed out. And this object I attain by the use-of a saturatedsolution of a salt containing an excess of the salt in solid phase. i

The nature of the invention will be more fully explained in the specification and more particularly pointed out in the claims.

In the drawings which form a part of the speciication- Fig. 1 is a plan View of a container to which .the invention. is applied, the cover being removed;

Fig. 2 is a perspective view of a porous carrier; and

Fig. 3 is a perspective view of the device shown in Flig. 2 as used in practice. InF ig. 1 the box 10 is chosen to represent generally a container for absorbent material such as above referred to. A.dja-.

cent one side wall is secured by cleats 11 a slab '12.

The slab 12 is made of porous material. So far as the general purpose of the invention is concerned, any chemically inert porous material may be used. In practice, however, I prefer a solid body pf porous material for reasons to be more fully explained. The slab 12 or any other porous solid body has the purpose to receive a solution of a salt within its pores, the solution being held therein by capilla attraction. The solution, the function o which has been pointed out above, is applied in such quantity as regards thel ercentage of voids in the mass that it wil always be so held even when ay considerable quantity of water has been absorbed. In other words, the solution is of such consistency that it is capable of taking up more water and the quantity is soproportioned relatively to the holdlng capacity of the body that such additional water can be safely held -by capillary attraction.

The solution may' frequently be more conveniently introduced by using a solution of a concentration and at a temperature such that on cooling it would deposit the excess solid salt in the desired proportions, thus producing a saturated solution containing some of the solid salt.

The salt solution and the quantity thereof is, of course chosen with respect to a desired de ree of relative humidity which may be di erent for different materials tobe protected. Thus for tobacco a relative humidity y of 50% te 65% is most desirable While cake and bread require a humidity of from 80% to 95%.

A -salt solution to be applicable for cigars or tobacco for instance must be such that' it absorbs water when the humidity rises above some equilibriumfpoint between 50 and 65%` and gives off water when the humidity falls below this point. f

Thus the system K2CO31.5H2O+ saturated solution has a humidity equilibrium pointo (at all ordinary indoor temperatures)I` about midway within this range, while the system arranged mentari. y

KCNS saturated solution gives a value near the lower limit of this range.

Experiment has shown, for example/that a system containing a saturated solution of potassium carbonate and some of the salt in solid phase, will maintain a practically uni# form relative humidity of 57%, while absorbing water between the limits of two *tenths to nine tenths of the weight of the anhydrous salt, or while giving up water between these same limits.

' lllhere is thus a Wide range during which the humidity may remainunchanged or in equilibrium condltion.

'Ihe selection of the particular salt best suited for a particular material is a matter with'which experts are fully acquainted and need not be described in detail.

As previously stated, while generally any porous body may be used as a carrier` of the solution, I prefer inv practice a porous solid body because it has greater retentive capacity, is mechanically more desirableand more convenient for handling. I prefer a material This porous material maybe applied in l any form. It is preferably used in the shape of slabs as indicated in the drawings, and y thata slab may be easily removed from the container for the proper readjustment of its moisture content.

rIhese slabs are preferably encased in a perforated cover 13 made of metal or other material to keepythem out of contact with the material contained.

As above referred to the form and application of the invention shown in the drawing is merely generally' representative. It is not necessary to refer particularly to other embodiments, different applications, different containers or different arrangements of the porous body in the container. The inventlon roper is not materially affected b suchifferences and modifications.

In Whatever form the invention may be embodied, itis based upon the fact that the material reacting upon the moisture content of a porous solid body, resents a considerably larger surface to t e atmosphere 1ihanv ach when contained in any other way. pore is so to speak a mmute container in itself which has the practical advantage that it will hold its content in all positions. f Due to the Vlar material e device is quickly responsive to chan s in the moisture content of the surroun Jng atmosphere. l

effective surface .of the reacting menen g I am aware that it has been proposed to tieliy constant relative humidity in a ges, use partiell dehydrated salts in solid form which consists in bringing in Contact with (see U. S. haten-t No. 949,701), which are the gas a salt contained in the ores of a l5 in effect a mixture of hydrated and anhyorous solid body artly as a, soli and part- 5 drous salts. y in saturated so ation.,

l claim: 3, A device for maintaining a substan- 1. The method of maintaining a, substantiatlly constant relative humidit in a as, tially constant relative humidity in a. ges, comprising a porous body hol ing wit in 20 which consists in bringing1 in Contact with its pores a salt partly as a solid end partly lo the gas a saturated solution of a salt conin saturated solution. taining an excess of the salt. In testimony whereof, I eflix m signature.

2. The method of maintaining a substan- JASPER WII-ylITING. 

